4′-[2-(Trifluoromethyl)phenyl]-2,2′:6′,2′′-terpyridine
نویسندگان
چکیده
منابع مشابه
4′-[4-(Pyridin-2-yl)phenyl]-2,2′:6′,2′′-terpyridine
In the title compound, C(26)H(18)N(4), each ring is almost planar with maximum deviation of 0.012 (5) Å. In the crystal, mol-ecules are stacked by weak C-H⋯π inter-actions, forming a three-dimensional framework.
متن کامل(4′-Ethynyl-2,2′:6′,2′′-terpyridine)(2,2′:6′,2′′-terpyridine)ruthenium(II) bis(hexafluoridophosphate) acetonitrile disolvate
The title heteroleptic bis--terpyridine complex, [Ru(C(15)H(11)N(3))(C(17)H(11)N(3))](PF(6))(2)·2CH(3)CN, crystallized from an acetonitrile solution as a salt containing two hexa-fluoridophosphate counter-ions and two acetonitrile solvent mol-ecules. The Ru(II) atom has a distorted octa-hedral geometry due to the restricted bite angle [157.7 (3)°] of the two mer-arranged N,N',N''-tridendate lig...
متن کاملDiethyl [4-(2,2′:6′,2′′-terpyridine-4′-yl)phenyl]phosphonate
The title compound, C25H24N3O3P, was obtained by catalytic phospho-nation of 4'-(4-bromphen-yl)-2,2':6',2''-terpyridine. The terpyridine moiety is nearly planar, the dihedral angles between the central and the outer rings being 4.06 (9) and 5.39 (9)°. The N atoms in the two pyridine rings are oriented nearly anti-periplanar to that of the central ring. The benzene ring is rotated out of the pla...
متن کامل[4′-(4-Aminophenyl)-2,2′:6′,2′′-terpyridine]chloridopalladium(II) chloride
The Pd(II) atom in the complex cation of the title compound, [PdCl(C(21)H(16)N(4))]Cl, is coordinated by three N atoms derived from the terpyridine ligand and a chloride ion, which define a distorted PdClN(3) square-planar coordination geometry. In the crystal, the presence of N-H⋯Cl hydrogen bonds involving the amino H atom and chloride anions link two cations and two anions into a four-ion ag...
متن کامل4′-[2-(Trifluoromethyl)phenyl]-2,2′:6′,2′′-terpyridine
The title compound, C(22)H(14)F(3)N(3), is a versatile tridentate N-donor ligand consisting of a terpyridyl (terpy) molecule substituted in the 4'-position by a phenyl group, itself substituted in an ortho-position by a bulky trifluoro-methyl group. The phenyl ring is twisted as a result of steric inter-actions involving the bulky trifluoro-methyl substituent. This is reflected in the dihedral ...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2009
ISSN: 1600-5368
DOI: 10.1107/s1600536809002384